International Journal For Multidisciplinary Research
E-ISSN: 2582-2160
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A Widely Indexed Open Access Peer Reviewed Multidisciplinary Bi-monthly Scholarly International Journal
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Volume 6 Issue 6
November-December 2024
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Bis and Mono Halide Bismuth(III) O,O’-Ditolyl Dithiophosphates
Author(s) | Seema Maheshwari |
---|---|
Country | India |
Abstract | Bis and mono halide bismuth(III) O,O’-ditolyl dithiophosphate complexes of the type [Bi{S2P(OR)2}nCl3-n] (where R = o-, m-, p-C6H4Me; n = 1-2) were synthesized by the reactions of Bismuth(III) chloride with ammonium ditolyldithiophosphasphates in 1:2 and 1:1 stoichiometric ratio. These novel complexes were characterized by elemental analysis, IR, 1H NMR and 31P NMR spectroscopy. On the basis of comparison with the earlier reported literatutre distorted trigonal bipyramidal geometry (tbp) may be proposed for the complexes corresponds to [(o-, m- or p-MeC6H4O)2PS2BiCl2] while an octahedral geometry for the complexes [{(o-,m- or p-MeC6H4O)2PS2}2BiCl]. |
Keywords | Bis and mono halide, Bismuth Complexes, Dithiophosphates |
Field | Lainnya |
Published In | Volume 3, Issue 6, November-December 2021 |
Published On | 2021-11-28 |
Cite This | Bis and Mono Halide Bismuth(III) O,O’-Ditolyl Dithiophosphates - Seema Maheshwari - IJFMR Volume 3, Issue 6, November-December 2021. |
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E-ISSN 2582-2160
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IJFMR DOI prefix is
10.36948/ijfmr
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