Bis and Mono Halide Bismuth(III) O,O’-Ditolyl Dithiophosphates

Author(s)	Seema Maheshwari
Country	India
Abstract	Bis and mono halide bismuth(III) O,O’-ditolyl dithiophosphate complexes of the type [Bi{S2P(OR)2}nCl3-n] (where R = o-, m-, p-C6H4Me; n = 1-2) were synthesized by the reactions of Bismuth(III) chloride with ammonium ditolyldithiophosphasphates in 1:2 and 1:1 stoichiometric ratio. These novel complexes were characterized by elemental analysis, IR, 1H NMR and 31P NMR spectroscopy. On the basis of comparison with the earlier reported literatutre distorted trigonal bipyramidal geometry (tbp) may be proposed for the complexes corresponds to [(o-, m- or p-MeC6H4O)2PS2BiCl2] while an octahedral geometry for the complexes [{(o-,m- or p-MeC6H4O)2PS2}2BiCl].
Keywords	Bis and mono halide, Bismuth Complexes, Dithiophosphates
Field	Lainnya
Published In	Volume 3, Issue 6, November-December 2021
Published On	2021-11-28
Cite This	Bis and Mono Halide Bismuth(III) O,O’-Ditolyl Dithiophosphates - Seema Maheshwari - IJFMR Volume 3, Issue 6, November-December 2021.

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