International Journal For Multidisciplinary Research

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Transforming Prussian Blue Analogues: The Future-Centric Pathway to Rise of Thin Layered Double Hydroxides for Superior Water Oxidation: An Overview

Author(s) MANOJ KUMAR, RAGHVENDRA PRATAP SINGH
Country India
Abstract Prussian blue analogues (PBAs)[1–5] have exhibited great performance towards electrochemical water oxidation because of their high activity and stability. However, there were some challenges because of their limited surface area and less accessible active sites. Herein this work, we have explored the synthesis of a Prussian blue analogue-based thin layered double hydroxide (PBA-TLDH)[6–9] through a reconstruction method. The (PBA-TLDH) possessed high surface area and a large number of active sites for enhanced electrochemical water oxidation. These PBA-LDH materials were well characterized by X-ray diffraction, Fourier transform infrared spectroscopy (FT-IR), transmission electron microscopy (TEM), and electrochemical techniques[1,7,10–12]. The PBA-TLDH materials had a well-defined thin layered structure with the PBAs uniformly distributed in the interlayer spaces of the LDHs. The PBA-LDH catalyst showed enhanced electrocatalytic activity towards water oxidation, with a very low overpotentials up to 240 mV and current density of 10 mA cm-2,[9,13–16] have been achieved which is significantly lower than that of the pristine PBAs. Moreover, these thin layered double hydroxides material showed excellent stability over large electrochemical cycle. This work provides a new strategy for the design and synthesis of highly active and stable electrocatalysts for water oxidation.
Keywords PBAs, LDHs, PBA-LDHs, Electrocatalyst, Water oxidation, Reconstruction, etc
Field Chemistry
Published In Volume 6, Issue 5, September-October 2024
Published On 2024-10-23
Cite This Transforming Prussian Blue Analogues: The Future-Centric Pathway to Rise of Thin Layered Double Hydroxides for Superior Water Oxidation: An Overview - MANOJ KUMAR, RAGHVENDRA PRATAP SINGH - IJFMR Volume 6, Issue 5, September-October 2024. DOI 10.36948/ijfmr.2024.v06i05.29213
DOI https://doi.org/10.36948/ijfmr.2024.v06i05.29213
Short DOI https://doi.org/g8pnnm
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